iRecovery
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iRecovery offers round-the-clock telehealth consultations with licensed psychologists and board-certified physicians, available nationwide for medication-assisted treatment of opioid use disorder. Their model stacks therapy and med management, with flexibility to match intensity to your needs, and they advertise availability outside standard business hours.
This fits if you live in a rural or underserved area where finding a local MAT provider is impossible, or if you need care on an irregular schedule. The emphasis on Ph.D.-level psychology (not just basic counselors) appeals to people who want depth in the talking part of treatment.